Search results for "mass [bottom]"
showing 10 items of 681 documents
Demethanization of aqueous anaerobic effluents using a polydimethylsiloxane membrane module: Mass transfer, fouling and feasibility
2017
Abstract The performance, fouling and feasibility of a polydimethylsiloxane hollow fibre membrane module for in situ methane degasification from the effluent of an Expanded Granular Sludge Bed anaerobic reactor has been investigated. Experiments at different operational conditions were carried out (liquid flow, sweep gas flow and vacuum pressure) with maximum removal efficiency (77%) at lowest flow-rate (0.4 L h−1), highest vacuum gauge pressure (−800 mbar) and liquid flowing in lumen side. Mass transport analysis denoted a considerably higher methane transfer than that predicted (attributed to liquid oversaturation). An enhancement factor for liquid phase has been proposed to correlate the…
La ética como coartada / 1
2007
Predicting breakthrough of vanadium in fixed-bed absorbent columns with complex groundwater chemistries: A multi-component granular ferric hydroxide−…
2020
Granular ferric hydroxide (GFH) is often used for fixed bed adsorbent (FBA) columns in groundwater purification units around the world to remove arsenate contaminations. Groundwater can contain also other toxic (e.g., antimonite and vanadate) and non-toxic oxo-anions (phosphate and silicic acid) that are known to affect FBA lifetimes. Therefore, understanding the breakthrough of toxic compounds intended for removal by FBA is essential to their design, and is important to predict accurately breakthrough curves (BTCs) for FBAs in waterworks to plan future operating costs. Rapid small-scale column tests (RSCCT) and pilot-scale FBA were used to simulate vanadate BTCs for complex groundwater che…
Scale-up and viscosity effects on gas–liquid mass transfer rates in unbaffled stirred tanks
2018
Abstract The interest in the process industry on unbaffled stirred tanks has greatly expanded in the last years because they may bring about significant advantages in a number of applications, including biochemical, food and pharmaceutical processes where the presence of baffles is undesirable for several reasons. Despite their application potential, unbaffled vessels still lack fundamental information, due to the fact that only recently their capabilities have started being dug out. The lack of information on scale up effects is possibly the main reason hindering practical applications. In this work the influence of vessel size and liquid viscosity on the mass transfer performance in unbaf…
Modeling of a continuous photocatalytic reactor for isovaleraldehyde oxidation: Effect of different operating parameters and chemical degradation pat…
2013
International audience; An investigation of isovaleraldehyde (ISOV) photocatalytic oxidation was conducted at initial concentrations ranging from 25 to 150 mg/m3 and different relative humidities (5-90% RH) in order to characterize the process performances close to indoor air conditions. Experiments were carried out in two different reactors: cylinder and flat-plate photoreactor (planar reactor) at different air gap (20-60 mm) and gas residence times (0.67-5.0 s). A plug flow reactor system was developed in order to perform kinetic studies of (i) isovaleraldehyde removal, (ii) selectivity of CO2, (iii) byproducts formation and removal. It appears that ISOV removal efficiencies increased wit…
Oxidation of organics in water in microfluidic electrochemical reactors: Theoretical model and experiments
2011
The electrochemical oxidation of organics in water performed in micro reactors on boron doped diamond (BDD) anode was investigated both theoretically and experimentally in order to find the influence of various operative parameters on the conversion and the current efficiency CE of the process. The electrochemical oxidation of formic acid (FA) was selected as a model case. High conversions for a single passage of the electrolytic solution inside the cell were obtained by operating with proper residence times and low distances between cathode and anode. The effect of initial concentration, flow rate and current density was investigated in detail. Theoretical predictions were in very good agr…
Electrochemical treatment of aqueous solutions containing one or many organic pollutants at boron doped diamond anodes. Theoretical modeling and expe…
2012
The electrochemical oxidation of organics in water at boron doped diamonds (BDD) was experimentally investigated with the aim to discuss the correlations among the conversion of the pollutants and the instantaneous current efficiency ICE with the operative conditions. A simple theoretical model previously developed for the oxidation of oxalic acid accounting for the cases of mass transfer control, oxidation reaction control and mixed kinetic regimes was adopted and extended to challenge its predictive capability in the case of organics of different nature and in systems with more pollutants. A quite good agreement, between theoretical predictions and experimental data pertaining to the elec…
Isotope fractionation of zinc in the paddy rice soil-water environment and the role of 2’deoxymugineic acid (DMA) as zincophore under Zn limiting con…
2021
Non-traditional stable isotope systems are increasingly used to study micronutrient cycling and acquisition in terrestrial ecosystems. We previously proposed for zinc (Zn) a conceptual model linking observed isotope signatures and fractionations to biogeochemical processes occurring in the rice soil environment and we suggested that 2’deoxymugineic acid (DMA) could play an important role for rice during the acquisition of Zn when grown under Zn limiting conditions. This proposition was sustained by the extent and direction of isotope fractionation observed during the complexation of Zn with DMA synthesised in our laboratory. Here we report a new set of experimental data from field and labor…
The Bossons glacier protects Europe's summit from erosion
2013
13 pages; International audience; The contrasting efficiency of erosion beneath cold glacier ice, beneath temperate glacier ice, and on ice-free mountain slopes is one of the key parameters in the development of relief during glacial periods. Detrital geochronology has been applied to the subglacial streams of the north face of the Mont-Blanc massif in order to estimate the efficiency of erosional processes there. Lithologically this area is composed of granite intruded at ~303 Ma within an older polymetamorphic complex. We use macroscopic features (on ~10,000 clasts) and U-Pb dating of zircon (~500 grains) to establish the provenance of the sediment transported by the glacier and its subgl…
Monitoring glacier elevation and volume changes with digital photogrammetry and GIS at Gepatschferner glacier, Austria
2006
Digital elevation models of Gepatschferner in Northern Tyrol, Austria were obtained with digital photogrammetry from high altitude stereo photo pairs and by digitizing an analogue topographic glacier map, for 1990 and 1971, respectively. A difference map was calculated to identify regions of glacier elevation increases and decreases corresponding to glacier mass gain and loss. While the glacier tongue below 2600 m showed mainly increases in glacier surface elevation as compared to 1971, the remaining glacier thickness experienced both increases and decreases. The accumulation zone above 3200 m contained several extreme cases of morphological features with altitude changes>+30 m. While the i…